We review a recent experimental campaign to study the interaction physics of petawatt laser pulses incident at relativistic intensities on solid targets. The campaign was performed on the 500 J sub-picosecond petawatt laser at the Rutherford Appleton Laboratory. An extensive suite of optical, x-ray, and particle diagnostics was employed to characterise the processes of laser absorption, electron generation and transport, thermal and K-alpha x-ray generation, and proton acceleration.