Results are given of the experimental investigation of three-particle correlation for liquid plasma-dust structures formed in the electrode layer of a capacitive rf discharge. The obtained three-particle correlation functions for experimental and numerical data are analysed and compared with the superposition approximation. The forming of clusters of macroparticles in plasma-dust systems being analysed is revealed. The experiments in heat transfer were performed in plasma of a capacitive radio-frequency (rf) discharge in argon (P ≈ 20 Pa) with particles 4 µm in mean diameter. The results are given of an experimental investigation of processes of heat transfer for fluid dust structures in rf-discharge. The analysis of steady-state, and unsteady-state heat transfer are used to obtain the thermal conductivity and diffusivity constants.