AbstractIn the design of ITER-FEAT, several candidate materials are foreseen for plasma-facing components of the divertor (tungsten, carbon fibre-reinforced composites (CFC), molybdenum) and the first wall (beryllium). In the view of accidental scenarios such as a loss of coolant accident or a loss of vacuum accident the reaction between these materials and steam or air remains a safety concern. To provide kinetic data, describing the chemical reactivity of plasma-facing materials in air and steam, we used coupled thermogravimetry/quadrupole mass spectrometry. In this paper we present the results of a screening investigation that compares the oxidation rates of tungsten, molybdenum, CFC and beryllium in the temperature range 300–700 °C. From the thermogravimetry and mass spectrometry results we obtained the reaction rates as a function of temperature. For the metals tungsten, molybdenum and beryllium, a transition is observed between protective oxidation at lower temperatures and non-protective oxidation at higher temperatures. This transition temperature lies in the range 500–550 °C for tungsten and molybdenum, which is lower than for beryllium. At above temperatures 550 °C, the oxides formed on molybdenum and tungsten volatilise. This increases the oxidation rate dramatically and can lead to mobilisation of activation products in a fusion reactor. We also performed experiments on both undoped CFC and CFC doped with 8–10% silicon. The influence of silicon doping on the chemical reactivity of CFC's in air is discussed.