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A study of tritium behavior in lithium oxide by ion conductivity measurements

Kenji Noda, Yoshinobu Ishii, Hisayuki Matsui, Hideo Ohno, Hitoshi Watanabe1989年Fusion Engineering and DesignIF 1.7出版社

Ion conductivity of lithium oxide (Li2O) irradiated with oxygen ions was measured to obtain information about the effects of irradiation on the behavior of lithium ions and tritium. The conductivity around 490 K decreased with the ion fluence, while around 440 K it increased. The decrease around 490 K and the increase around 440 K were assumed to be attributed to the F+ centers and the unspecified radiation defects, respectively. From the point of view that the rate determinant in the mechanism of diffusion of lithium ions in Li2O leading to the ion conductivity is the same as that of tritium, the diffusivity of tritium is assumed to be as follows: the diffusivity of tritium is decreased by the F+ centers in the range from 490 K to the temperature at which almost all of F+ centers are recovered, while it is increased around 440 K by the unspecified radiation defects. In addition, effects of the irradiation on valence states of tritium (i.e., T+, T−) were discussed in terms of the radiation defects.

日本語訳

リチウム酸化物(Li₂O)に酸素イオンを照射した際の、リチウムイオンおよびトリチウムの挙動に対する照射効果に関する情報を得るため、酸素イオンを照射したリチウム酸化物(Li₂O)のイオン伝導度を測定した。約490 Kにおける伝導度はイオン照射量の増加とともに減少したが、約440 Kでは増加した。約490 Kでの減少はF⁺中心に起因し、約440 Kでの増加は特定されない照射欠陥に起因するものと推測された。Li₂Oにおけるリチウムイオンの拡散機構において律速段階がイオン伝導度の場合と同一であるという観点から、トリチウムの拡散係数は以下のように推測される。すなわち、トリチウムの拡散係数は、約490 KからほぼすべてのF⁺中心が回復する温度までの範囲ではF⁺中心によって減少し、約440 Kでは特定されない照射欠陥によって増加する。さらに、トリチウムの価数状態(すなわち、T⁺、T⁻)に対する照射効果について、照射欠陥の観点から考察した。

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