The process of plasma deceleration during the injection of supersonic plasma flow across the magnetic field of an arched configuration is experimentally demonstrated. Pulsed plasma microwave emission in the electron cyclotron frequency range is observed. It is shown that the frequency spectrum of plasma emission is determined by the position of the deceleration region in the magnetic field of the magnetic arc, and its bandwidth is defined by the magnetic field inhomogeneity in the deceleration region. The observed emission can be related to the cyclotron mechanism of wave generation by non-equilibrium energetic electrons in the dense plasma.