An experimental study of the extraordinary mode (X mode) absorption at the third electron cyclotron harmonic frequency has been performed on the TCV tokamak in plasmas preheated by X mode at the second harmonic. Full single pass absorption of injected X3 power was measured with X2 preheating in co-current drive (CO-ECCD). The measured absorption exceeds that predicted by the linear ray tracing code TORAY-GA by more than a factor of 2 for the CO-ECCD case. Experimental evidence indicates that a large fraction of the X3 power is absorbed by electrons in an energetic tail created by the X2 ECCD preheating.